Hydrogen Generator : Electrolysis, Solar, Homemade & Cornish Hydrogen Generators

UmpquaEnergy.com > Hydrogen Generator > Cornish-Hydrogen-Generaor.html

  Cornish Hydrogen Generator

The Cornish Hydrogen Generator is an interesting proposition, but not energy effecient from a cradle to grave standpoint.  The premise is that scrap aluminum is combined with sodium hydroxide and water which actually causes a chemical reaction strong enough to break apart the water into hydroxy gas.  Alumina Oxide remains which could be smelted and turned back into aluminum.  At face value it looks like a great recycling scheme but after measuring the amount of electricity it take to get the alumina back into aluminum.  In addition, the process is very dangerous as the chemical reaction is difficult to control.  The more heat the more reactive which emits more heat and so on.  Note:  If your kids start buying a lot of Red Devil Lye, be advised that they could do serious damage and no one likes a homeland security raid on a sunny afternoon.

-

-

-

-

Below:  This is a Cornish Hydrogen Generator
Hydroxy Doesn't Burn, It Explodes

 

Cornish Hydrogen Generator

There are just three components to the basic cornish hydrogen generator.  Obviously the system can be enhanced, but we are only going to cover the reaction that occurs when you mix aluminum, water and sodium hydroxide (Red Devil Lye).

Note:  This is a dangerous reaction.  This is not a feasible generator for a home generator or for transportation as the reaction is nearly impossible to control. 

Do not build the cornish hydrogen generator unless you are a quaified professional with appropriate safety gear.

To build a cornish hydrogen generator, start with a plastic bucket (called a reactor)approx. one gallon in size.  Loosely seal the top with a hose that comes out (to capture the gas) and feed the tube into a bubbler.  A bubbler is a quart sized container filled 3/4 with water.  The tube from the reactor should go to the bottom of the bubbler so that the gas bubbles from the base of the bubbler all the way to the top.  Fix another tube on the bubbler and connect a fuel hose to it.  The tip of the fuel hose should be metal (copper flexible tubing).

Note:  The bubbler is a stop gap between the source of fuel (reactor) and the flame.  The last thing you want is to have a flame reach your reactor.  You will meltdown your reactor which is not a good thing as your mixture will flow and burn and water will not put it out, only feed the fire more.

Once you have your reactor, bubbler and fuel line constructed, it is now time to start a reaction.

Put a quart of water, aluminum and red devil lye into the reactor.  Seal the lid of the reactor.  Pick up the reactor and stir around the red devil lye so that it desolves into the water.  Set down the reactor and watch bubbles start to form on the aluminum.  The rate should increase within 2-3 minutes.  If not, add more lye.  We are not going to give you the amount to put in, this is your experiment and if your experiment goes horribly wrong we don't want a lawsuit saying "But the website said to put X amount in".

You now have a cornish hydrogen generator.  The reactor should produce enough pressure to push gas through the bubbler.  We found that we had to elevate the bubbler so that less pressure is needed.  The bubbler will eventually be filled with gas and push all of the air out of the system and at some point you will have pure Brown's Gas.  Once that happens, you should be able to crimp your copper tubing so that instead of being round it is flat (not closed off).  This will allow you to ignite the gas coming out of the tube and it should carry a flame so long as the reaction continue in the reactor.

 

Will It Scale?
If an engineering firm can figure out how to control the reaction on a larger scale, then you may have a feasible reactor.  The aluminium feedstock would need to be from reclamation of waste aluminum from sources that normally would be wasted by sitting in the landfill. 

Sea, waste or tap water is combined with aluminum and a chemical matrix that initiates an exothermic reaction within proprietary machinery that is computer controlled to manage the reaction within ASME pressure vessels.  The process separates pure hydrogen from the water, creates steam and changes the scrap aluminum into valuable and pure alumina.  The steam drives turbines, which creates electricity.  The hydrogen fuels internal combustion engines attached to a power generator, which also creates electricity.  The process emits no harmful emissions into the atmosphere as only potable water and pure oxygen is released.

Below is a breakdown comparing the current recycling process compared to how the Cornish Hydrogen Generator could split out materials into base components that could be sold to individual markets.

Cornish Hydrogen Generator Compared to Current Recycling Process

MARKET SUMMARY
The following market summary is based on Umpqua Energy's cursory research, potential revenue from electricity, alumina, oxygen and water will fluctuate.

Scrap Aluminum
Scrap aluminum has a commodity market, as there is a ready supply of purchasers willing to buy limitless quantities.  There is not much use for scrap aluminum besides smelting into new aluminum, which is cheaper than mining bauxite, processing to alumina then smelting alumina into new aluminum.  Preparations for scrap aluminum to enter the marketplace include an energy consuming process of baling, shredding, crushing, compacting and cleaning.  Recycler’s processing facilities operate on a 2-4% margin and sell to customers who a) pay their bills and b) have the highest bid price and has a market value of $.60/lb.

Alumina
Alumina is not part of a commodity market as there is not a ready supply of purchasers who will buy limitless quantities.  Most importantly, alumina can be smelted back into aluminum.  Alumina can be sold domestically or internationally for between $.72/lb at smelter grade and $2,000/lb at chemical grade.  Chemical grade revenue can be garnered only if performed in a certified lab environment.  There are many uses for alumina as a raw material to be used in the creation of cement, ceramics, toothpaste, deodorants, inks and abrasive slurries. 

Hydrogen
Hydrogen is not part of a commodity market as there is not a ready supply of purchasers who will buy limitless quantities.  Transport and storage issues must be resolved prior to having the ability to sell into a marketplace.  When the market is established, the prices will be reliant on oil and natural gas pricing as the majority of research development grants have gone to reformation projects.  Hydrogen can be used as a fuel to power gensets which can produce electricity to supply to customers.

Oxygen
Oxygen is not part of a commodity market as there is not a ready supply of purchasers who will buy limitless quantities.  Accessing the market would require compressing, liquefying, bottling and transporting the product to market.  Current plans for the excess oxygen would be to feed it into the induction systems of the internal combustion engine or vent it into atmosphere.

Water
A thorough market study is recommended to compare the costs and revenues associated with desalinization plants being constructed along our coastlines.  Converting industrial wastewater to potable water has intrinsic value and with appropriate proximity to a client revenue could be garnered as a service to the neighboring facility.  The water could be bottled and sold or recycled back into the process to reduce consumption.

Electricity
Electricity has a commodity market, as there is a ready supply of purchasers willing to buy limitless quantities.  Renewable, green and emission free energy is in high demand.  Federal, State and Local Governments have initiated policy change to purchase 100% green energy over the next 20 years.  To encourage the market to meet that challenge, tax incentives and accelerated depreciation schedules have been put into place.  In addition, various States fund self-generation initiatives.  California has taken the lead in being the most green energy and self-generation friendly State in our union.  In 2004 they have funded a rebate program worth $175mm to those who self generate power.  Rebates can be applied for through the utility companies who also certify the workmanship of the machinery.


 


 

 

It may be possible to 7x the value of scrap aluminum by running it through this process.  Taking aluminum out of the recycling stream will bring a project like this negative attention.  If a company can use the increased value of the individual components to fund seperation efforts within landfills and/or promote recycling in communities that do not have bottle bills, then they may gain support.  Alumina can be smelted back into aluminum but at a larger energy penalty than simply re-melting the scrap aluminimum back into pure aluminimum.

 

 

UmpquaEnergy.com > Hydrogen Generator > Cornish-Hydrogen-Generaor.html

 

 (c) UmpquaEnergy.com 2007. All Rights Reserved.